, Wang, Li , Zhang, Jiliang , Zhou, Zhongmin , Li, Chongwen , Chen, Bingbing , Lioz, Etgar , Cui, Guanglei , and Pang, Shuping . 2017.
“Ch3Nh2 Gas Induced (110) Preferred Cesiumcontainingperovskite Films With Reduced Pbi6Octahedron Distortion And Enhanced Moisturestability”. J. Mater. Chem. A, 2017,5, Pp. 4803–4808.
Abstract We report here the discovery of a fancy interaction between cesium iodide (CsI) and methylamine (CH3NH2) due to the presence of the hydrogen bond. The formed CsI$xCH3NH2 is a liquid phase, which facilitates the large scale fabrication of highly uniform cesium-containing perovskite films with strong (110) preferred orientation by the CH3NH2 gas healing process. With this method, at most 10% nonpolar Cs cations could fully dope into the crystal lattice and extremely enhance the interaction of the inorganic framework with a moresymmetrical PbI6 octahedron, resulting in obvious improvement in moisture stability under continuous illumination.
{An important property of hybrid layered perovskite is the possibility to reduceits dimensionality to provide wider band gap and better stability. In this work,2D perovskite of the structure (PEA)2(MA)n–1PbnBr3n+1 has been sensitized,where PEA is phenyl ethyl-ammonium, MA is methyl-ammonium, and usingonly bromide as the halide. The number of the perovskite layers has beenvaried (n) from n = 1 through n = ∞. Optical and physical characterizationverify the layered structure and the increase in the band gap. The photovoltaicperformance shows higher open circuit voltage (Voc) for the quasi 2D perovskite(i.e.
Y. Huang, Aharon, S. , Rolland, A. , Pedesseau, L. , Durand, O. , Etgar, L. , and Even, J. . 2017.
“Influence Of Schottky Contact On The C-V And J-V Characteristicsof Htm-Free Perovskite Solar Cells”. Epj Photovoltaics, 2017,8, Pp. 85501.
Abstract Abstract The influence of the Schottky contact is studied for hole transport material (HTM) freeCH3NH3PbI3 perovskite solar cells (PSCs), by using drift-diffusion and small signal models. The basiccurrent-voltage and capacitance-voltage characteristics are simulated in reasonable agreement with experimentaldata. The build in potential of the finite CH3NH3PbI3 layer is extracted from a Mott-Schottkycapacitance analysis. Furthermore, hole collector conductors with work-functions of more than 5.5 eV areproposed as solutions for high efficiency HTM-free CH3NH3PbI3 PSCs.
Ravi K Misra, Cohen, Bat-El , Iagher, Lior , and Lioz, Etgar . 2017.
“Low-Dimensional Organic&Ndash;Inorganic Halide Perovskite:structure, Properties, And Applications”. Chemsuschem, 2017,10, Pp. 3712 – 3721.
Chongwen Li, Zhou, Yuanyuan , Wang, Yue Chang Li, Zong, Yingxia , Lioz, Etgar , Cui, Guanglei , Padture, Nitin P, and Pang, Shuping . 2017.
“Methylammonium-Mediated Evolution Of Mixed-Organic-Cationperovskite Thin Films: A Dynamic Composition-Tuning Process”. Angew. Chem. Int. Ed., 2017,56, Pp. 7674 –7678.
Daniel Amgar, Wierzbowska, Małgorzata , Uvarov, Vladimir , Gutkin, Vitaly , and Lioz, Etgar . 2017.
“Novel Rubidium Lead Chloride Nanocrystals: Synthesis And Characterization”. Nano Futures, 1, Pp. 021002.
Daniel Amgar, , , Rotem, Dvir , Porath, Danny , and Lioz, Etgar . 2017.
“Tunable Length And Optical Properties Of Cspbx3 (X = Cl, Br, I)Nanowires With A Few Unit Cells”. Nano Letters, 2017, 17, Pp. 1007-1013.
Abstract {Perovskite nanostructures, both hybrid organo-metaland fully inorganic perovskites, have gained a lot of interest in the pastfew years for their intriguing optical properties in the visible region. Wereport on inorganic cesium lead bromide (CsPbBr3) nanowires (NWs)having quantum confined dimensions corresponding to 5 unit cells. Theaddition of various hydrohalic acids (HX