Abstract:

Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C–B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes. [["fid":26772,"view_mode":"default","type":"media","attributes":"height":"838","width":"719","alt":"MOLECULES1","class":"media-element file-default"]] 

Notes:

Invited Review This article belongs to the Special Issue New Insights in Diversity Oriented Synthesis