@article {74460,
	title = {High and Reversible Ammonia Uptake in Mesoporous Azolate Metal\&ndash;Organic Frameworks with Open Mn, Co, and Ni Sites},
	journal = {J. Am. Chem. Soc.},
	volume = {138 },
	year = {2016},
	note = {<p>\&nbsp;</p><p style="text-align: center;">[[{"fid":106180,"view_mode":"default","type":"media","attributes":{"height":"279","width":"500","title":"TOC Amonia sorption in MOFS","class":"media-element file-default"}}]]</p>},
	pages = {9401{\textendash}4},
	abstract = {A series of new mesoporous metal{\textendash}organic frameworks (MOFs) made from extended bisbenzenetriazolate linkers exhibit coordinatively unsaturated metal sites that are responsible for high and reversible uptake of ammonia. Isostructural Mn, Co, and Ni materials adsorb 15.47, 12.00, and 12.02 mmol of NH<sub>3</sub>/g, respectively, at STP. Importantly, these near-record capacities are reversible for at least three cycles. These results demonstrate that azolate MOFs are sufficiently thermally and chemically stable to find uses in recyclable sorption, storage, and potentially separation of chemically challenging and/or corrosive gases, especially when designed to exhibit a high density of open metal sites.},
	url = {https://pubs.acs.org/doi/abs/10.1021/jacs.6b05723},
	author = {Adam J. Rieth and Yuri Tulchinsky and Mircea Dinca}
}
