@article { ISI:000283391800030,
	title = {The Bicorannulenyl Dianion: A Charged Overcrowded Ethylene},
	journal = {Angewandte Chemie-International Edition},
	volume = {49},
	number = {41},
	year = {2010},
	note = {[["fid":"23895","view_mode":"default","type":"media","attributes":"height":"276","width":"1000","style":"width: 543px; height: 150px;","alt":"25. David Angew Chem 2010","title":"25. David Angew Chem 2010","class":"media-element file-default"]]},
	pages = {7538-7542},
	publisher = {WILEY-V C H VERLAG GMBH},
	type = {Article},
	address = {PO BOX 10 11 61, D-69451 WEINHEIM, GERMANY},
	abstract = {Super bowl: Bicorannulenyl, a large biaryl composed of two corannulene bowls, effectively becomes an overcrowded ethylene upon reduction to form a dianion (see picture). DFT calculations and NMR spectroscopic experiments reveal the double-bond character of the connection between the two bowls. Three stable diastereomers that interconvert through bowl inversions and central bond rotations were shown to exist.},
	keywords = {annulenes, carbanions, conformation analysis, conjugation, overcrowded ethylenes},
	issn = {1433-7851},
	doi = {10.1002/anie.201002515},
	author = {Eisenberg, David and Jackson, Edward A. and Quimby, Jennifer M. and Scott, Lawrence T. and Shenhar, Roy}
}
