@article {19404,
	title = {Spatially Heterogeneous Chlorine Incorporation in Organic\&minus;Inorganic Perovskite Solar Cells},
	journal = {Chemistry of Materials},
	volume = {2016,28},
	number = {18},
	year = {2016},
	pages = {6536{\textendash}6543},
	abstract = {Spatial heterogeneities in the chemical makeup of thin film photovoltaic devices are pivotal in determining device efficiency. We report the in-plane spatial distribution and degree of chlorine incorporation in organic-inorganic lead halide perovskite absorbers by means of nondestructive synchrotronbased nanoprobe X-ray fluorescence. The presence of chlorine is positively identified in CH3NH3PbI3 films synthesized with Clcontaining precursors and as an impurity in some films synthesized with nominally Cl-free precursors. The impurity may be introduced from precursors or as contaminants during film synthesis. The films formed from Cl-containing precursors contain roughly an order of magnitude higher amount of chlorine, with Cl:I values greater than 0.02 found whether Cl is present in either the organic or the inorganic precursor for both one- and two-step fabrication processes. A spatial variation in the Cl incorporation is observed within single particles and as well as between particles within a given film, and the standard deviation of the Cl:I ratio across the films is up to 30\% of the averagevalue. Understanding and controlling the heterogeneous distribution of chlorine in hybrid perovskite layers may offer a path to improve their photovoltaic performance.},
	author = {Yanqi Luo and Shany Gamliel and Sally Nijem and Aharon, Sigalit and Martin Holt and Benjamin Stripe and Volker Rose and Mariana I. Bertoni and Etgar Lioz and David P. Fenning}
}
